在二甲基甲酰胺(DMF) 中合成了Fe ( Ⅲ) 與一分子2 ,2′2 聯(lián)吡啶- 1 ,1′2 二氧化物(bipyO2 ) 的新化合物[ Fe (bipyO2) Cl2 ]Cl·1/ 6 bipyO2 。用元素分析、摩爾電導(dǎo)、紅外光譜和紫外光譜等方法測定了它的組成。用該配合物制作的傳感器對(duì)氨氣有極高的敏感性和選擇性。可用于氨氣泄漏報(bào)警和對(duì)環(huán)境中氨氣的實(shí)時(shí)監(jiān)測。
關(guān)鍵詞:傳感器; 2 ,22聯(lián)吡啶- 1 ,1′2 二氧化物; 配合物; 合成; 三氯化鐵

Abstract : The coordination compound of Fe( Ⅲ) with 2 ,22bipyridine - 1 ,12dioxide was synthesized , It was char2 acterized by elemental analysis , IR ,UV and molar conductivity. The gas sensitive property was studied ,the re2 sults indicated that the composition of the coordination compound is [ Fe(bipyO2) Cl2 ]Cl·1/ 6 bipyO2 . The sensor manufactured by coordination compound has very high sensitivity and selectivity to ammonia. It could be used in ammonia leak2alarm and in environment realtime supervising ammonia.
Key words :sensor ;2 ,2′2 bipyridine - 1 ,1′2 dioxide ;complex ;synthesis ;FeCl3